



ZS8100-HCl Process Hydrogen Chloride Analyzer
TDLAS diode-laser hydrogen chloride analyzer for waste-incineration CEMS (EU IED ≤10 mg/Nm³), chlor-alkali, PVC / VCM / EDC, and semiconductor CVD chlorosilane exhaust
- Range
- 0–50 / 0–200 / 0–5000 ppm
- Accuracy
- ±2 % FS or ±1 ppm
- Response (T90)
- <10 s
- Wetted Parts
- Hastelloy C-276
Overview
The ZS8100-HCl is an extractive TDLAS hydrogen chloride analyzer built for hot, wet, corrosive service — waste-incineration and hazardous-waste CEMS under the EU IED daily ELV of 10 mg/Nm³, chlor-alkali cell-room and compression-section monitoring, PVC / VCM / EDC monomer process tracking, semiconductor CVD chlorosilane (TCS / DCS) decomposition exhaust, and wet-scrubber abatement verification. A narrow-line near-IR diode-laser resolves HCl above the H₂O continuum and separates the HCl line from CO₂ / SO₂ / HF background where broadband NDIR can be constrained by wet acid-gas matrices. The measurement path runs through a heated sample line with Hastelloy C-276 wetted parts to preserve HCl integrity above its dew point.
- TDLAS single-line laser absorption — reagent-free optical cell; heated sample path remains a service item
- Laser-line selection separates HCl from H₂O continuum plus CO₂ / SO₂ / HF spectral background after matrix review
- Heated sample path + Hastelloy C-276 wetted parts preserve HCl integrity above dew point
- Multi-range firmware spans CEMS ppm (EU IED ≤10 mg/Nm³) to process %-range without optics change
Full Technical Specifications
Key Performance
| Metric | Value | Status |
|---|---|---|
| Range | 0–50 / 0–200 / 0–5000ppm (multi-range) | conditional* |
| Accuracy | ±2 % FS or ±1ppm (whichever greater) | conditional* |
| Response (T90) | <10 s | conditional* |
| Detection Limit | <0.5ppm (CEMS-useful) | conditional* |
* Industry-typical TDLAS HCl values — target scope pending own-brand hardware sign-off; confirm against final datasheet at quotation.
Measurement
| Specification | Value |
|---|---|
| Measuring Principle | TDLAS (Tunable Diode Laser Absorption Spectroscopy) |
| Target Wavelength | Near-IR ≈ 1.74 μm (HCl overtone band) |
| Measurement Range | 0–50 ppm / 0–200 ppm / 0–5000 ppm (multi-range) |
| Lower Detection Limit | <0.5 ppm (CEMS-useful) |
| Accuracy | ±2 % FS or ±1 ppm (whichever greater) |
| Repeatability | ≤1 % FS |
| Response Time (T90) | <10 s |
| Matrix Resolution | H₂O continuum / CO₂ / SO₂ / HF handled through laser-line selection and application matrix review |
Sample System
| Specification | Value |
|---|---|
| Sampling Mode | Extractive via heated probe + heated sample line (above HCl dew point) |
| Wetted Parts | Hastelloy C-276 on sample path; PTFE on sealing surfaces |
| Sample Temperature | Up to 180 °C (heated line; application-dependent) |
| Sample Pressure | -30 to +500 mbar g |
| Recommended Conditioning | ZS-SCS-800 Hastelloy heated sampling system (stack / CEMS duty) |
| Platform Variant | TDLAS HCl is also available on an alternative analyzer-platform footprint for skid-fit projects — confirmed during application engineering review |
Environmental
| Specification | Value |
|---|---|
| Operating Temperature | -20 °C to +50 °C |
| Storage Temperature | -40 °C to +70 °C |
| Humidity | 0–95 % RH (non-condensing) |
| Ingress Protection | IP65 (standard) / IP66 (field enclosure) |
Electrical
| Specification | Value |
|---|---|
| Power Supply | 100–240 VAC, 50/60 Hz, 100 W max (heated line separate) |
| Analog Output | 2 × 4–20 mA (isolated, configurable) |
| Digital Output | RS-485 Modbus RTU / HART 7 (optional) |
| Relay Outputs | 4 × SPDT (alarm, fault, maintenance, range) |
| Display | 5″ color TFT with local touchscreen HMI |
Physical
| Specification | Value |
|---|---|
| Dimensions (W×H×D) | 483 × 177 × 420 mm (19″ rack) / field enclosure optional |
| Weight | ≈16 kg (rack) / ≈34 kg (field enclosure) |
| Housing Material | Powder-coated aluminum enclosure; Hastelloy C-276 wetted parts on sample path |
| Mounting | 19″ rack (4U) / wall-mount / field enclosure |
Certifications
| Specification | Value |
|---|---|
| CE Marking | EU equipment directive compliance (standard) |
| Hazardous Area | ATEX / IECEx — Conditional scope (confirmed per project) |
| CEMS Type-Approval | MCERTS (UK) / US EPA PS-18 HCl CEMS — target scope, confirmed per project |
| EMC | EN 61326-1 |
| Quality System | ISO 9001:2015 manufactured |
| Application Standards | EU IED BAT / US EPA Method 321 / DIN EN 1911 (incineration HCl CEMS); OSHA PEL 5 ppm (workplace HCl safety) |
Where This Analyzer Fits
This model is mapped to the following industry applications and process duties.
Deployment Environments
Common process environments where this model is evaluated.
Certification Scope
Standards are listed with scope and status so engineering review can verify the applicable wetted-material, regulatory method, and hazardous-area case. Performance and CEMS approvals are shown as target scope pending own-brand hardware and documentation sign-off; hazardous-area scope is tracked as a Conditional engineering-review path, not a default catalogue claim.
| Standard | Scope | Variant | Status | Document |
|---|---|---|---|---|
| CE (EU declaration of conformity) | EU equipment directive compliance (standard) | Project variant | target | On request |
| MCERTS / US EPA PS-18 (HCl CEMS) | MCERTS (UK) / US EPA PS-18 HCl CEMS — confirmed per project | Project variant | target | On request |
| ATEX / IECEx hazardous area | Engineering-review scope; confirmed per project | Project variant | conditional | On request |
| ISO 9001:2015 | Quality management system — manufactured under ISO 9001:2015 | Project variant | approved | On request |
Request Documentation
Request technical datasheets, user manuals, certificates, and application notes for this model.
Evidence Notes
Wet-stack HCl heated-line architecture
For waste-incineration and chlor-alkali duties, the architecture keeps the HCl sample above dew point through a heated extractive path and Hastelloy wetted handling so the optical measurement is not dependent on a cool-dry CO / NOx sample chain.
Technical & Engineering Details
Secondary engineering detail — expand each topic for the full measurement, envelope, sample-system, calibration, integration, maintenance and application evidence.
01 Measurement Principle and Limits
How the measurement is bounded
TDLAS measures HCl on a near-IR overtone line while the heated extractive path keeps wet acid-gas matrices above the HCl dew point.
Rejects
- Ambient or cool-dry sampling for wet HCl stack gas
- Electrochemical HCl safety-alarm positioning as the default process/CEMS path
- Unreviewed NDIR substitution for wet incineration matrices
Requires
- Heated probe and heated sample line
- Hastelloy C-276 wetted sample path
- H₂O continuum and acid-gas matrix review
- ZS-SCS-800 or equivalent heated corrosive sampling for stack / CEMS duty
Interferents and Limits
- H₂O continuum
- SO₂ and CO₂ background
- HF overlap in mixed acid-gas service
- HCl loss into condensate on cold surfaces
02 Operating Envelope
Use these limits as selection inputs, then confirm sample condition, ambient exposure, and materials before quotation.
- Ambient / cool-dry sampling for wet HCl stack gas
- Condensing sample path
- Unreviewed hazardous-area scope
03 Sample System Boundary
Sampling mode, conditioning components, and exclusions define where the analyzer responsibility ends and the sample system begins.
- Heated probe
- Heated sample line above HCl dew point
- Hastelloy C-276 sample path
- ZS-SCS-800 heated sampling system
- Peltier cool-dry chain for wet HCl duty
- Generic CO / NOx sample chain reused for HCl without heated path review
04 Calibration & Validation
Calibration method, interval, traceability, and audit support are shown only when structured data is available.
Zero / Span Method
Project-specific HCl zero/span and field audit plan
Interval
Site-specific
Reference Methods
US EPA Method 321 reference context; DIN EN 1911 stationary-source HCl context
Span Gas Traceability
Project-specific calibration gas or validation media
Audit Support
- US EPA Method 321 reference context
- DIN EN 1911 stationary-source HCl context
- QAL2 / AST planning support when CEMS scope is included
05 I/O & Integration
Signal outputs and communication interfaces shown from the published specification fields on this product page.
Output
4–20 mA / RS-485 Modbus / HART
Analog Output
2 × 4–20 mA (isolated, configurable)
Digital Output
RS-485 Modbus RTU / HART 7 (optional)
Relay Outputs
4 × SPDT (alarm, fault, maintenance, range)
DAHS Review Note
Confirm protocol map, channel naming, alarm states, and reporting format during project integration review.
06 Maintenance & Spares site-specific
Tasks, consumables, and access items are shown only when structured maintenance data is available.
- Inspect heated probe and sample line
- Check Hastelloy wetted path and seals
- Verify HCl zero/span setup
- Review condensation and acid carryover risk
- HCl-compatible filters
- Heated-line service parts
- Project-specific calibration gas or validation media
07 Application Evidence
Application context from complex industrial environments.
Application Context
Municipal waste-to-energy plants retrofitting boiler-house CEMS to meet EU IED BAT-AEL face the legacy NDIR HCl response time of ~30 minutes, which leaves operators without the dynamic-range visibility needed to manage chloride-driven upset events.
Architecture Response
A ZS8100-HCl TDLAS analyzer on an extractive heated-line loop at the ESP outlet — paired with a ZS-SCS-800 heated sample probe — delivers <10 s HCl response, so chloride upsets are visible to the operator within the same minute they occur and BAT-AEL upset response can be tightened.
Frequently Asked Questions
Can the ZS8100-HCl sample ambient / cool-dry instead of heated 180 °C?
HCl is strongly water-soluble and has a dew point well above ambient in wet stack gas — a 10 %vol H2O incineration flue stream condenses to an acidic film on any cold surface, stripping HCl into the drop-out before the cell ever sees the molecule. EN 1911 (stationary-source HCl reference method) and US EPA Method 321 both require heated sample paths held 20 °C above the local dew point, typically ≥180 °C, with HCl-resistant wetted parts. A Peltier cool-dry chain removes the water but carries the HCl with it — the classic failure mode when operators reuse a CO / NOx chain for HCl duty. The ZS8100-HCl is therefore specified with the ZS-SCS-800 Hastelloy heated sampling system as a matched set; ambient / cool-dry deployment is not a supported configuration.
How does the ZS8100-HCl stay selective on wet incineration flue gas where SO2, CO2 and HF all absorb in IR?
The near-IR HCl overtone line at ~1.74 μm sits in a laser-resolved window where the TDLAS system tunes across the line centre at MHz-scale resolution. Broadband NDIR photometers can struggle to separate the HCl feature from the H2O continuum or the CO2 / SO2 / HF overlap in this matrix. The TDLAS first-derivative fit separates the wing absorbers and reports HCl against the local line shape. For incineration CEMS this supports EPA Method 321-aligned engineering review, QAL2 preparation, and AST field-audit planning.
Which measurement range do I order for EU IED ≤10 mg/Nm³ incineration duty?
The EU IED Annex VI daily ELV for incineration HCl is 10 mg/Nm³ referenced to 11 %vol O2 dry — approximately 6 ppm at reference conditions. The 0–50 ppm firmware range is the primary CEMS range for this duty; the 0–200 ppm range handles boiler upsets and the 0–5000 ppm range handles chlor-alkali cell-room and PVC / VCM process vent loops. Firmware switches the configured range without optics change, so one analyzer carries both the compliance range and the process-upset range on the same signal chain. Report units (ppm vs mg/m³, dry vs wet, 11 %vol O2 normalized) are set in the HMI and locked behind operator-level access.
Is the ZS8100-HCl MCERTS / PS-18 certified today?
CE marking and ISO 9001:2015 manufacturing are standard. MCERTS (UK, certifying body Sira) and US EPA Performance Specification 18 (gaseous HCl CEMS) are listed as target scope, pending completion of GESHINE own-brand hardware and documentation sign-off — certificate numbers and validity windows are not published yet. The analyzer is therefore specified as a PS-18 / MCERTS QAL1 candidate rather than an already-certified CEMS; the ATEX / IECEx hazardous-area scope is Conditional, confirmed per project before order commitment. Sales engineering will confirm the current certification status, including issuing body and certificate number, before project commit.
Is the ZS8100-HCl available on a different analyzer platform for skid-fit projects?
Yes. The ZS8100-HCl runs on the ZS8100-series platform (O2 / HF / C2H2 family in 19-inch rack / field enclosure) and is positioned as the HCl flagship for incineration CEMS and chlor-alkali. The same TDLAS HCl measurement is also available on an alternative analyzer-platform footprint for projects where a different skid and mechanical envelope fits better — typical in refinery sulfur-recovery vent and chlor-alkali compression sections already standardized on that platform. Measurement performance is comparable TDLAS in both cases; the choice is driven by skid / panel standardization, not by accuracy or range. Application engineering will confirm the platform match during the sizing review.
Review ZS8100-HCl against site conditions
Send gas range, sample temperature, pressure, moisture, and certification needs before final model selection.

