Industrial Series: ZS8100-HCl

ZS8100-HCl Process Hydrogen Chloride Analyzer

TDLAS diode-laser hydrogen chloride analyzer for waste-incineration CEMS (EU IED ≤10 mg/Nm³), chlor-alkali, PVC / VCM / EDC, and semiconductor CVD chlorosilane exhaust

Range
0–50 / 0–200 / 0–5000 ppm
Accuracy
±2 % FS or ±1 ppm
Response (T90)
<10 s
Wetted Parts
Hastelloy C-276
Product Overview

Overview

The ZS8100-HCl is an extractive TDLAS hydrogen chloride analyzer built for hot, wet, corrosive service — waste-incineration and hazardous-waste CEMS under the EU IED daily ELV of 10 mg/Nm³, chlor-alkali cell-room and compression-section monitoring, PVC / VCM / EDC monomer process tracking, semiconductor CVD chlorosilane (TCS / DCS) decomposition exhaust, and wet-scrubber abatement verification. A narrow-line near-IR diode-laser resolves HCl above the H₂O continuum and separates the HCl line from CO₂ / SO₂ / HF background where broadband NDIR can be constrained by wet acid-gas matrices. The measurement path runs through a heated sample line with Hastelloy C-276 wetted parts to preserve HCl integrity above its dew point.

Key Highlights
  • TDLAS single-line laser absorption — reagent-free optical cell; heated sample path remains a service item
  • Laser-line selection separates HCl from H₂O continuum plus CO₂ / SO₂ / HF spectral background after matrix review
  • Heated sample path + Hastelloy C-276 wetted parts preserve HCl integrity above dew point
  • Multi-range firmware spans CEMS ppm (EU IED ≤10 mg/Nm³) to process %-range without optics change

Full Technical Specifications

Key Performance

Key Performance metrics for ZS8100-HCl
Metric Value Status
Range 0–50 / 0–200 / 0–5000ppm (multi-range) conditional*
Accuracy ±2 % FS or ±1ppm (whichever greater) conditional*
Response (T90) <10 s conditional*
Detection Limit <0.5ppm (CEMS-useful) conditional*

* Industry-typical TDLAS HCl values — target scope pending own-brand hardware sign-off; confirm against final datasheet at quotation.

Measurement

Measurement specifications for ZS8100-HCl
SpecificationValue
Measuring PrincipleTDLAS (Tunable Diode Laser Absorption Spectroscopy)
Target WavelengthNear-IR ≈ 1.74 μm (HCl overtone band)
Measurement Range0–50 ppm / 0–200 ppm / 0–5000 ppm (multi-range)
Lower Detection Limit<0.5 ppm (CEMS-useful)
Accuracy±2 % FS or ±1 ppm (whichever greater)
Repeatability≤1 % FS
Response Time (T90)<10 s
Matrix ResolutionH₂O continuum / CO₂ / SO₂ / HF handled through laser-line selection and application matrix review

Sample System

Sample System specifications for ZS8100-HCl
SpecificationValue
Sampling ModeExtractive via heated probe + heated sample line (above HCl dew point)
Wetted PartsHastelloy C-276 on sample path; PTFE on sealing surfaces
Sample TemperatureUp to 180 °C (heated line; application-dependent)
Sample Pressure-30 to +500 mbar g
Recommended ConditioningZS-SCS-800 Hastelloy heated sampling system (stack / CEMS duty)
Platform VariantTDLAS HCl is also available on an alternative analyzer-platform footprint for skid-fit projects — confirmed during application engineering review

Environmental

Environmental specifications for ZS8100-HCl
SpecificationValue
Operating Temperature-20 °C to +50 °C
Storage Temperature-40 °C to +70 °C
Humidity0–95 % RH (non-condensing)
Ingress ProtectionIP65 (standard) / IP66 (field enclosure)

Electrical

Electrical specifications for ZS8100-HCl
SpecificationValue
Power Supply100–240 VAC, 50/60 Hz, 100 W max (heated line separate)
Analog Output2 × 4–20 mA (isolated, configurable)
Digital OutputRS-485 Modbus RTU / HART 7 (optional)
Relay Outputs4 × SPDT (alarm, fault, maintenance, range)
Display5″ color TFT with local touchscreen HMI

Physical

Physical specifications for ZS8100-HCl
SpecificationValue
Dimensions (W×H×D)483 × 177 × 420 mm (19″ rack) / field enclosure optional
Weight≈16 kg (rack) / ≈34 kg (field enclosure)
Housing MaterialPowder-coated aluminum enclosure; Hastelloy C-276 wetted parts on sample path
Mounting19″ rack (4U) / wall-mount / field enclosure

Certifications

Certifications specifications for ZS8100-HCl
SpecificationValue
CE MarkingEU equipment directive compliance (standard)
Hazardous AreaATEX / IECEx — Conditional scope (confirmed per project)
CEMS Type-ApprovalMCERTS (UK) / US EPA PS-18 HCl CEMS — target scope, confirmed per project
EMCEN 61326-1
Quality SystemISO 9001:2015 manufactured
Application StandardsEU IED BAT / US EPA Method 321 / DIN EN 1911 (incineration HCl CEMS); OSHA PEL 5 ppm (workplace HCl safety)

Where This Analyzer Fits

This model is mapped to the following industry applications and process duties.

Incineration CEMS
Chlor-Alkali
PVC / VCM / EDC
Semiconductor CVD

Deployment Environments

Common process environments where this model is evaluated.

Waste-incineration and hazardous-waste CEMS (EU IED ≤10 mg/Nm³ HCl)
Chlor-alkali cell-room and compression / drying section monitoring
PVC / VCM / EDC monomer process and vent-gas tracking
Semiconductor CVD chlorosilane (TCS / DCS) decomposition exhaust
Wet-scrubber upstream / downstream abatement verification

Certification Scope

Standards are listed with scope and status so engineering review can verify the applicable wetted-material, regulatory method, and hazardous-area case. Performance and CEMS approvals are shown as target scope pending own-brand hardware and documentation sign-off; hazardous-area scope is tracked as a Conditional engineering-review path, not a default catalogue claim.

Certification scope matrix for ZS8100-HCl
Standard Scope Variant Status Document
CE (EU declaration of conformity) EU equipment directive compliance (standard) Project variant target On request
MCERTS / US EPA PS-18 (HCl CEMS) MCERTS (UK) / US EPA PS-18 HCl CEMS — confirmed per project Project variant target On request
ATEX / IECEx hazardous area Engineering-review scope; confirmed per project Project variant conditional On request
ISO 9001:2015 Quality management system — manufactured under ISO 9001:2015 Project variant approved On request
CE Corrosive-Service Wetted Parts MCERTS / PS-18 (pending)

Request Documentation

Request technical datasheets, user manuals, certificates, and application notes for this model.

Evidence Notes

case-study

Wet-stack HCl heated-line architecture

For waste-incineration and chlor-alkali duties, the architecture keeps the HCl sample above dew point through a heated extractive path and Hastelloy wetted handling so the optical measurement is not dependent on a cool-dry CO / NOx sample chain.

Technical / Engineering Details

Technical & Engineering Details

Secondary engineering detail — expand each topic for the full measurement, envelope, sample-system, calibration, integration, maintenance and application evidence.

01 Measurement Principle and Limits

How the measurement is bounded

TDLAS measures HCl on a near-IR overtone line while the heated extractive path keeps wet acid-gas matrices above the HCl dew point.

Rejects

  • Ambient or cool-dry sampling for wet HCl stack gas
  • Electrochemical HCl safety-alarm positioning as the default process/CEMS path
  • Unreviewed NDIR substitution for wet incineration matrices

Requires

  • Heated probe and heated sample line
  • Hastelloy C-276 wetted sample path
  • H₂O continuum and acid-gas matrix review
  • ZS-SCS-800 or equivalent heated corrosive sampling for stack / CEMS duty

Interferents and Limits

  • H₂O continuum
  • SO₂ and CO₂ background
  • HF overlap in mixed acid-gas service
  • HCl loss into condensate on cold surfaces
02 Operating Envelope

Use these limits as selection inputs, then confirm sample condition, ambient exposure, and materials before quotation.

Sample Temperature
up to 180 C
heated sample line maximum; project-dependent
Ambient Temperature
-20-50 C
Wetted Materials
Hastelloy C-276, PTFE
Outside This Envelope
  • Ambient / cool-dry sampling for wet HCl stack gas
  • Condensing sample path
  • Unreviewed hazardous-area scope
03 Sample System Boundary

Sampling mode, conditioning components, and exclusions define where the analyzer responsibility ends and the sample system begins.

Sampling Mode
extractive
Boundary Components
  • Heated probe
  • Heated sample line above HCl dew point
  • Hastelloy C-276 sample path
  • ZS-SCS-800 heated sampling system
Boundary Exclusions
  • Peltier cool-dry chain for wet HCl duty
  • Generic CO / NOx sample chain reused for HCl without heated path review
04 Calibration & Validation

Calibration method, interval, traceability, and audit support are shown only when structured data is available.

Zero / Span Method

Project-specific HCl zero/span and field audit plan

Interval

Site-specific

Reference Methods

US EPA Method 321 reference context; DIN EN 1911 stationary-source HCl context

Span Gas Traceability

Project-specific calibration gas or validation media

Audit Support

  • US EPA Method 321 reference context
  • DIN EN 1911 stationary-source HCl context
  • QAL2 / AST planning support when CEMS scope is included
05 I/O & Integration

Signal outputs and communication interfaces shown from the published specification fields on this product page.

Output

4–20 mA / RS-485 Modbus / HART

Analog Output

2 × 4–20 mA (isolated, configurable)

Digital Output

RS-485 Modbus RTU / HART 7 (optional)

Relay Outputs

4 × SPDT (alarm, fault, maintenance, range)

DAHS Review Note

Confirm protocol map, channel naming, alarm states, and reporting format during project integration review.

06 Maintenance & Spares site-specific

Tasks, consumables, and access items are shown only when structured maintenance data is available.

Service Tasks
  • Inspect heated probe and sample line
  • Check Hastelloy wetted path and seals
  • Verify HCl zero/span setup
  • Review condensation and acid carryover risk
Consumables
  • HCl-compatible filters
  • Heated-line service parts
  • Project-specific calibration gas or validation media
07 Application Evidence

Application context from complex industrial environments.

Case Study Municipal Waste-to-Energy / Incineration CEMS

Application Context

Municipal waste-to-energy plants retrofitting boiler-house CEMS to meet EU IED BAT-AEL face the legacy NDIR HCl response time of ~30 minutes, which leaves operators without the dynamic-range visibility needed to manage chloride-driven upset events.

Architecture Response

A ZS8100-HCl TDLAS analyzer on an extractive heated-line loop at the ESP outlet — paired with a ZS-SCS-800 heated sample probe — delivers <10 s HCl response, so chloride upsets are visible to the operator within the same minute they occur and BAT-AEL upset response can be tightened.

BAT-AEL Upset Response TDLAS extractive · <10 s HCl response
Selection Questions

Frequently Asked Questions

Can the ZS8100-HCl sample ambient / cool-dry instead of heated 180 °C?

HCl is strongly water-soluble and has a dew point well above ambient in wet stack gas — a 10 %vol H2O incineration flue stream condenses to an acidic film on any cold surface, stripping HCl into the drop-out before the cell ever sees the molecule. EN 1911 (stationary-source HCl reference method) and US EPA Method 321 both require heated sample paths held 20 °C above the local dew point, typically ≥180 °C, with HCl-resistant wetted parts. A Peltier cool-dry chain removes the water but carries the HCl with it — the classic failure mode when operators reuse a CO / NOx chain for HCl duty. The ZS8100-HCl is therefore specified with the ZS-SCS-800 Hastelloy heated sampling system as a matched set; ambient / cool-dry deployment is not a supported configuration.

How does the ZS8100-HCl stay selective on wet incineration flue gas where SO2, CO2 and HF all absorb in IR?

The near-IR HCl overtone line at ~1.74 μm sits in a laser-resolved window where the TDLAS system tunes across the line centre at MHz-scale resolution. Broadband NDIR photometers can struggle to separate the HCl feature from the H2O continuum or the CO2 / SO2 / HF overlap in this matrix. The TDLAS first-derivative fit separates the wing absorbers and reports HCl against the local line shape. For incineration CEMS this supports EPA Method 321-aligned engineering review, QAL2 preparation, and AST field-audit planning.

Which measurement range do I order for EU IED ≤10 mg/Nm³ incineration duty?

The EU IED Annex VI daily ELV for incineration HCl is 10 mg/Nm³ referenced to 11 %vol O2 dry — approximately 6 ppm at reference conditions. The 0–50 ppm firmware range is the primary CEMS range for this duty; the 0–200 ppm range handles boiler upsets and the 0–5000 ppm range handles chlor-alkali cell-room and PVC / VCM process vent loops. Firmware switches the configured range without optics change, so one analyzer carries both the compliance range and the process-upset range on the same signal chain. Report units (ppm vs mg/m³, dry vs wet, 11 %vol O2 normalized) are set in the HMI and locked behind operator-level access.

Is the ZS8100-HCl MCERTS / PS-18 certified today?

CE marking and ISO 9001:2015 manufacturing are standard. MCERTS (UK, certifying body Sira) and US EPA Performance Specification 18 (gaseous HCl CEMS) are listed as target scope, pending completion of GESHINE own-brand hardware and documentation sign-off — certificate numbers and validity windows are not published yet. The analyzer is therefore specified as a PS-18 / MCERTS QAL1 candidate rather than an already-certified CEMS; the ATEX / IECEx hazardous-area scope is Conditional, confirmed per project before order commitment. Sales engineering will confirm the current certification status, including issuing body and certificate number, before project commit.

Is the ZS8100-HCl available on a different analyzer platform for skid-fit projects?

Yes. The ZS8100-HCl runs on the ZS8100-series platform (O2 / HF / C2H2 family in 19-inch rack / field enclosure) and is positioned as the HCl flagship for incineration CEMS and chlor-alkali. The same TDLAS HCl measurement is also available on an alternative analyzer-platform footprint for projects where a different skid and mechanical envelope fits better — typical in refinery sulfur-recovery vent and chlor-alkali compression sections already standardized on that platform. Measurement performance is comparable TDLAS in both cases; the choice is driven by skid / panel standardization, not by accuracy or range. Application engineering will confirm the platform match during the sizing review.

Review ZS8100-HCl against site conditions

Send gas range, sample temperature, pressure, moisture, and certification needs before final model selection.